EFFECT OF MnO2 CONCENTRATIONS ON PHYSICAL PROPERTIES OF THE (K0.436Na0.5Li0.064)Nb0.92Sb0.08O3 LEAD-FREE PIEZOELECTRIC CERAMIC SYSTEM

Authors

  • Lê Anh Thi Trường Đại học Khoa học, Đại học Huế
  • Võ Duy Dần Đại học Huế

Abstract

This paper presents the results of the synthesis on the physical properties of the lead-free piezoelectric ceramics of the (K0.436Na0.5Li0.064)Nb0.92Sb0.08O3 (KNLNS) doped with x % wt MnO2 (x = 0;2;4;6;8;10 % wt). The effect of MnO2 concentrations on physical properties of the ceramics has been studied and the best concentration of 6 % wt MnO2 determined. The physical properties of the ceramic composition of this MnO2 concentration are good such as ρ = 4.45 g/cm3, kt = 3.8, kp = 2.8, tanδ = 0.16, ε = 645, d31 =38.2 pC/N. The transfer of polymorphic phase transition (PPT) into rather low temperature (440C) and the effect of polarizing temperature on the physical properties of the ceramic system have been also studied and discussed.

References

. B. Jaffe, W. R. Cook, and H. Jaffe, Piezoelectric Ceramics, Academic Press, London, 1971.

. Barbara Malic, Lead free Piezoelectrics Based on Alkaline Niobates Synthesis, Sintering and Microstructure, Acta Chim. Slov. 55, (2008), 719-726.

. 3.Ding quan xiao, Progresses and further considerations on the research of perovskite lead free piezoelectric ceramics, Journal of Advanced Dielectrics, Vol. 1, No. 1, (2011), 33-40.

. Dragan Damjanovic, Naama Klein,Jin Li and Victor Porokhonskyy, What Can Be Expected From Lead – Free Piezoelectric Materials? Functional Materials Letters, Vol.3, No.1, (2010), 5-13.

. Henry Ekene Mgbemere, Ralf-Peter Herber, Gerold A. Schneider, Effect of MnO2 on the Dielectric and Piezoelectric properties of Alkaline Niobate based Lead-Free Piezoelectric Ceramics, Journal of European Society, Volume 29, No.6, (2009), 1729-1733.

. Ju”rgen Ro”del, Wook Jo, Klaus T.P. Seifert, Eva-Maria Anton, and Torsten Granzow, Dragan Damjanovic, Perpective on the Development of Lead free Piezoceramics, J.Am.Ceram. Soc, 92, (2009), 1153-1177.

. Peng QI, Jinfeng Wang, Bao quan Ming, Juan Du, Xinghua Liang and Limei Zheng, Piezoelectric Properties of (Na0.5K0.5-xLix)NbO3 Ceramics, J. Mater. Sci. Technol, Vol. 23, (2007), 833-836.

. Pornsuda Bomlaia, Phase transition behaviour and dielectric properties of Na0.5K0.5NbO3-LiTaO3-LiSbO3 lead-free piezoceramic, Science Asia, (2009), 35.

. Takafumi Maeda, Norihoto Takiguchi, Mutstuo Ishikawa, Tobias Hemsel, Takeshi Morita, (K,Na)NbO3 lead-free piezoelectric ceramics synthesized from hydrothermal powders, Materials Letters, 64, (2010), 125-128.

. Y. Wang, D. Damjanovic, N. Klein, E. Hollenstein, and N. Setter, Compositional Inhomogeneity in Li and Ta Modified (K,Na)NbO3 Ceramics, J. Am. Ceram. Soc. (2007), 3485 – 3489.

Published

2013-03-27