Fabrication and evaluation of some electrochemical properties of screen-printed electrodes for use in electrochemical analysis

Tóm tắt

Three types of conductive inks, including Ceres, Acheson carbon inks, and Ag/AgCl ink, were utilized to fabricate screen-printed electrodes (SPEs) on a 0.4 mm thick polyethylene terephthalate substrate using a screen-printing technique. To enhance the electrical conductivity, the printed electrodes were cured at 80°C for 90 minutes. The basic electrochemical properties of the self-made SPEs using these conductive inks were determined, evaluated, and compared with commercial SPEs from Metrohm. Although the electroactive surface areas of the self-made SPEs were not significantly different from those of the commercial SPEs, the heterogeneous electron transfer rates on the surfaces of self-made SPEs using Ceres and Acheson inks were inferior to those of the commercial SPEs. However, after pre-condition by applying a potential of +1.2 V for 180 s in a 2 M Na2CO3 solution, the electrochemical properties of the self-made SPEs, including the active surface areas and heterogeneous electron transfer rates, were significantly improved and became better than those of the commercial SPEs.

https://doi.org/10.26459/hueunijns.v133i1B.7226

Tài liệu tham khảo

  1. Renedo OD, Alonso-Lomillo MA, Martínez MJA. Recent developments in the field of screen-printed electrodes and their related applications. Talanta. 2007;73(2):202-19.
  2. Hart JP, Wring SA. Screen-printed voltammetric and amperometric electrochemical sensors for decentralized testing. Electroanalysis. 1994;6(8):617-24.
  3. Liu X, Yao Y, Ying Y, Ping J. Recent advances in nanomaterial-enabled screen-printed electro-chemical sensors for heavy metal detection. TrAC Trends in Analytical Chemistry. 2019;115:187-202.
  4. González-Costas JM, Gómez-Fernández S, García J, González-Romero E. Screen-printed electrodes-based technology: Environmental application to real time monitoring of phenolic degradation by phytoremediation with horseradish roots. Science of The Total Environment. 2020;744:140782.
  5. Phillips C, Al-Ahmadi A, Potts S-J, Claypole T, Deganello D. The effect of graphite and carbon black ratios on conductive ink performance. Journal of Materials Science. 2017;52(16):9520-30.
  6. Cui G, Yoo JH, Lee JS, Yoo J, Uhm JH, Cha GS, et al. Effect of pre-treatment on the surface and electrochemical properties of screen-printed carbon paste electrodes. Analyst. 2001;126(8):1399-403.
  7. García-Miranda Ferrari A, Foster CW, Kelly PJ, Brownson DAC, Banks CE. Determination of the Electrochemical Area of Screen-Printed Electrochemical Sensing Platforms. Biosensors. 2018;8(2).
  8. Zhu P, Zhao Y. Cyclic voltammetry measurements of electroactive surface area of porous nickel: Peak current and peak charge methods and diffusion layer effect. Materials Chemistry and Physics. 2019;233:60-7.
  9. Willfahrt A, Fischer T, Huebner G. Improving the electrical performance and mechanical properties of conductive ink on thin compound substrate. Journal of Print and Media Technology Research. 2016;5:7-14.
  10. Fletcher S. Screen-Printed Carbon Electrodes. Electrochemistry of Carbon Electrodes. Electrochemistry of Carbon Electrodes. Wiley; 2015. p. 425-44.
  11. Suresh RR, Lakshmanakumar M, Arockia Jayalatha JBB, Rajan KS, Sethuraman S, Krishnan UM, et al. Fabrication of screen-printed electrodes: opportunities and challenges. Journal of Materials Science. 2021;56(15):8951-9006.
  12. Joyce M, Pal L, Hicks R, Agate S, Williams TS, Ray G, et al. Custom tailoring of conductive ink/substrate properties for increased thin film deposition of poly(dimethylsiloxane) films. Journal of Materials Science: Materials in Electronics. 2018;29(12):10461-70.
  13. Foster CW, Kadara RO, Banks CE. Fundamentals of Screen-Printing Electrochemical Architectures. In: Banks CE, Foster CW, Kadara RO, editors. Screen-Printing Electrochemical Architectures. Cham: Springer International Publishing; 2016. p. 13-23.
  14. Harris AR, Newbold C, Cowan R, Wallace GG. Insights into the Electron Transfer Kinetics, Capacitance and Resistance Effects of Implantable Electrodes Using Fourier Transform AC Voltammetry on Platinum. Journal of The Electrochemical Society. 2019;166(12):G131
  15. Wang J, Tian B, Nascimento VB, Angnes L. Performance of screen-printed carbon electrodes fabricated from different carbon inks. Electrochimica Acta. 1998;43:3459-65.
  16. Wang J. Analytical Electrochemistry. 3rd ed. USA: John Wiley & Sons; 2006.
Creative Commons License

công trình này được cấp phép theo Creative Commons Ghi công-Chia sẻ tương tự 4.0 License International .

Bản quyền (c) 2024 Array