Facile synthesis of 3D Fe2O3 nanostructures: sponge-like cube shape and bird nest-like architecture
PDF

Keywords

3D nanostructure
sponge-like nanocube
bird nest-like architecture
iron oxide

How to Cite

1.
Tran QP, Ho VMH, Tran TH, Nguyen DC. Facile synthesis of 3D Fe2O3 nanostructures: sponge-like cube shape and bird nest-like architecture. hueuni-jns [Internet]. 2023Dec.30 [cited 2024Dec.22];132(1D):55-62. Available from: https://jos.hueuni.edu.vn/index.php/hujos-ns/article/view/7055

Abstract

The hierarchical nanostructures (3D) with their large specific surface area and abundant pores usually possess unique physical and chemical properties for various important applications. In this report, we have introduced simple and scalable routes to successfully synthesize 3D iron oxide nanostructures, including porous cubes and bird nest-like architecture. The 3D sponge-like Fe2O3 nanocubes were formed by an annealing process of perfect Prussian Blue (PB) microcubes, which were built from small nanoparticles linked together. Whereas, the 3D bird nest-like Fe2O3 nanostructures were formed by the transformation of C@FeOOH nanoflower precursors, which were constructed by primary nanorods. The results indicated that the obtained materials show monodispersity, uniform morphology, ultra-porosity and extremely high specific surface area. With unique characteristics, the 3D Fe2O3 nanostructures could be potential candidates for various important fields such as catalysts, absorption and gas sensors.

https://doi.org/10.26459/hueunijns.v132i1D.7055
PDF

References

  1. Nguyen TD, Tang D, Acierno FD, Michal CA, MacLachlan MJ. Biotemplated Lightweight γ-Alumina Aerogels. Chem Mater. 2018;30:1602-09.
  2. Nai J, Lou XW. Hollow Structures Based on Prussian Blue and Its Analogs for Electrochemical Energy Storage and Conversion. Adv Mater. 2019;31(38):1706825.
  3. Wu Q, Wu G, Wang L, Hu W, Wu H. Facile synthesis and optical properties of Prussian Blue microcubes and hollow Fe2O3 microboxes. Mater Sci Semicond Process. 2015; 30:476-81.
  4. Wang H, Zhang X, Wang N, Li Y, Feng X, Huang Y, et al. Ultralight, scalable, and high-temperature–resilient ceramic nanofiber sponges. Sci Adv. 2017;3:1603170.
  5. Cuong ND, Hoa ND, Hoa TT, Khieu DQ, Quang DT, Quang VV, Hieu NV. Nanoporous hematite nanoparticles: Synthesis and applications for benzylation of benzene and aromatic compounds. J Alloys Compd. 2014;582:83-87.
  6. Kim HJ, Choi KI, Pan A, Kim ID, Kim HR, Kim KM, et al. Template-free solvothermal synthesis of hollow hematite spheres and their applications in gas sensors and Li-ion batteries. J Mater Chem. 2011;21:6549.
  7. Hu M, Belik AA, Imura M, Mibu K, Tsujimoto Y, Yamauchi Y. Synthesis of Superparamagnetic Nanoporous Iron Oxide Particles with Hollow Interiors by Using Prussian Blue Coordination Polymers. Chem Mater. 2012;24:2698-2707.
  8. Zhang C, Chen Z, Wang H, Nie Y, Yan J. Porous Fe2O3 Nanoparticles as Lithium-Ion Battery Anode Materials. ACS Appl. Nano Mater. 2021;4:8744-52.
  9. Teng Y, Zhang XF, Xu TT, Deng ZP, Xu YM, Huo LH, et al. A spendable gas sensor with higher sensitivity and lowest detection limit towards H2S: Porous α-Fe2O3 hierarchical tubule derived from poplar branch. Chem Eng J. 2020;392:123679.
  10. Liu X, Chen K, Shim JJ, Huang J. Facile synthesis of porous Fe2O3 nanorods and their photocatalytic properties. J Saudi Chem Soc. 2015;19:479-84.
  11. Krafft K.E., Wang C, Lin W, Metal-Organic Framework Templated Synthesis of Fe2O3/TiO2 Nanocomposite for Hydrogen Production. Adv Mater. 2012;24:2014-2018.
  12. Gao P, Liu R, Huang H, Jia X, Pan H, MOF-templated controllable synthesis of α-Fe2O3 porous nanorods and their gas sensing properties. RSC Adv. 2016;6:94699-705.
  13. Li Y, Zhou YX, Ma X, Jiang HL. A metal–organic framework-templated synthesis of γ-Fe2O3 nanoparticles encapsulated in porous carbon for efficient and chemoselective hydrogenation of nitro compounds. Chem Commun. 2016;52:4199-4202.
  14. Zhang L, Wu HB, Madhavi S, Hng HH, Lou XW. Formation of Fe2O3 Microboxes with Hierarchical Shell Structures from Metal–Organic Frameworks and Their Lithium Storage Properties. J Am Chem Soc. 2012;134(42):17388-91.
  15. Zhang L, Wu HB, Xu R, Lou XW. Porous Fe2O3 nanocubes derived from MOFs for highly reversible lithium storage. CrystEngComm. 2013;15:9332.
  16. Yao S, Zhang G, Zhang X, Zhao Y, Shi Z. Synthesis of α-Fe2O3 double-layer hollow spheres with carbon coating using carbonaceous sphere templates for lithium ion battery anodes. J Solid State Electrochem. 2021;25:267-278.
  17. Wang S, Wang L, Yang T, Liu X, Zhang J, Zhu B, et al. Porous α-Fe2O3 hollow microspheres and their application for acetone sensor. J Solid State Chem. 2010;183:2869-76.
  18. Nie Z, Wang Y, Zhang Y, Pan A. Multi-shelled α-Fe2O3 microspheres for high-rate supercapacitors. Sci China Mater. 2016;59:247-253.
  19. Parajuli D, Tanaka H, Sakurai K, Hakuta Y, Kawamoto T. Thermal Decomposition Behavior of Prussian Blue in Various Conditions. Materials (Basel). 2021;14:1151.
  20. Trinh LH, Khieu DQ, Long HT, Hoa TT, Quang DT, Cuong ND. A novel approach for synthesis of hierarchical mesoporous Nd2O3 nanomaterials. J. Rare Earths. 2017;35:677-82.
  21. Son LL, Cuong ND, Thi TTV, Hieu LT, Trung DD, et al. Konjac glucomannan-templated synthesis of three-dimensional NiO nanostructures assembled from porous NiO nanoplates for gas sensors, RSC Adv. 2019;9:9584-93.
  22. Li F, Zhang T, Gao X, Wang R, Li B. Coaxial electrospinning heterojunction SnO2/Au-doped In2O3 core-shell nanofibers for acetone gas sensor. Sensors Actuators B Chem. 2017;252:822-30.
  23. Li M, Li W, Liu S. Hydrothermal synthesis, characterization, and KOH activation of carbon spheres from glucose. Carbohydr Res. 2011;346:999-1004.
  24. Nguyen TD. From formation mechanisms to synthetic methods toward shape-controlled oxide nanoparticles. Nanoscale. 2013;5:9455.
Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Copyright (c) 2023 Array